3-nitrobenzylidene di(acetate) GMP Manufacturer Global Trade 29949-19-7 with Fast Delivery
- Molecular Formula: C11H11NO6
- Molecular Weight: 253.211
- Vapor Pressure: 2.62E-05mmHg at 25°C
- Melting Point: 72°C
- Refractive Index: 1.537
- Boiling Point: 358 °C at 760 mmHg
- Flash Point: 155 °C
- PSA： 98.42000
- Density: 1.323 g/cm3
- LogP: 2.24280
3-nitrobenzylidene di(acetate)(Cas 29949-19-7) Usage
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Synthesis Reference(s) |
The Journal of Organic Chemistry, 48, p. 1765, 1983 DOI: 10.1021/jo00158a036Tetrahedron Letters, 36, p. 601, 1995 DOI: 10.1016/0040-4039(94)02292-J |
InChI:InChI=1/C11H11NO6/c1-7(13)17-11(18-8(2)14)9-4-3-5-10(6-9)12(15)16/h3-6,11H,1-2H3
29949-19-7 Relevant articles
Solvent-free chemoselective synthesis of 1,1-diacetates catalyzed by Cu(NO3)2·3H2O
Heravi, Majid M.,Bakhtiari, Khadijeh,Tehrani, Maryam H.,Oskooie, Hossein A.
, p. 1121 - 1126 (2007)
1,1-Diacetates have been synthesized by ...
A stable intermediate: a new insight into the mechanism of Lewis acids-promoted formation of acylals from aldehydes
Yin, Liang,Zhang, Zhan-Hui,Wang, Yong-Mei
, p. 3119 - 3122 (2007)
Treatment of m-nitrobenzaldehyde with ac...
Solid superacids as catalysts for the synthesis of acylals from aldehydes and acetic anhydride
Lermontov,Yurkova
, p. 2561 - 2563 (2008)
Sulfated tin, aluminum, and titanium oxi...
Application of poly(Vinylbenzyltrimethylammonium tribromide) resin as an efficient polymeric catalyst in the acetalization and diacetylation of benzaldehydes
Han, Bingbing,Hu, Junjun,Li, Xianwei,Zheng, Zubiao
supporting information, p. 287 - 293 (2021/04/28)
The applications of a new supported trib...
Chemoselective synthesis of 1,1-diacetates under solvent-free condition using efficient heterogeneous ecofriendly catalyst: P2O5/kaolin
Rai, Nityanand,Sharma, Abha
, p. 340 - 344 (2019/05/21)
An efficient and chemoselective method f...
N-Propylsulfamic acid supported onto magnetic Fe3O4 nanoparticles (MNPs-PSA) as a green and reusable heterogeneous nanocatalyst for the chemoselective preparation and deprotection of acylals
Sajjadifar, Sami,Nasri, Parastoo
, p. 6677 - 6689 (2017/10/06)
Abstract: N-propylsulfamic acid supporte...
Microwave-assisted green synthesis of 1,1-diacetates (acylals) using selectfluor as an environmental-friendly catalyst under solvent-free conditions
Rezayati, Sobhan,Hajinasiri, Rahimeh,Erfani, Zahra
, p. 2567 - 2576 (2016/03/16)
An efficient and simple procedure has be...
29949-19-7 Process route
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108-24-7
acetic anhydride
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-
99-61-6
3-nitro-benzaldehyde
-
-
100-52-7
benzaldehyde
-
-
29949-19-7
1,1-diacetoxy-1-(3-nitrophenyl)methane
-
-
581-55-5
benzylidene 1,1-diacetate
| Conditions | Yield |
|---|---|
|
With
cross-linked polystyrene-supported aluminium triflate;
In
dichloromethane;
at 20 ℃;
for 1.15h;
chemoselective reaction;
|
93 %Chromat.
7 %Chromat. |
-
-
581-55-5
benzylidene 1,1-diacetate
-
-
29949-19-7
1,1-diacetoxy-1-(3-nitrophenyl)methane
-
-
6345-63-7
1-diacetoxymethyl-2-nitro-benzene
-
-
2929-91-1
4-nitrobenzylidene diacetate
| Conditions | Yield |
|---|---|
|
With
Nitrogen dioxide; ozone;
In
dichloromethane;
at 0 ℃;
Yields of byproduct given;
|
29949-19-7 Upstream products
-
108-24-7
acetic anhydride
-
99-61-6
3-nitro-benzaldehyde
-
581-55-5
benzylidene 1,1-diacetate
-
86119-84-8
phosphoric acid
29949-19-7 Downstream products
-
108-44-1
1-amino-3-methylbenzene
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614-48-2
(E)-3-nitrochalcone
-
99-61-6
3-nitro-benzaldehyde
-
23229-30-3
3-nitrophenyl-1,3-dithiolane
